The problem asks for the number of moles of $KMnO_4$ required to completely react with one mole of $FeC_2O_4$ in an acidic medium. The possible answers are provided as fractions.

Applied MathematicsChemical ReactionStoichiometryBalancing Equations
2025/7/13

1. Problem Description

The problem asks for the number of moles of KMnO4KMnO_4 required to completely react with one mole of FeC2O4FeC_2O_4 in an acidic medium. The possible answers are provided as fractions.

2. Solution Steps

The skeleton equation for the reaction in acidic medium is:
FeC2O4+KMnO4+H+Fe3++CO2+Mn2++H2OFeC_2O_4 + KMnO_4 + H^+ \rightarrow Fe^{3+} + CO_2 + Mn^{2+} + H_2O
First, balance the oxidation half-reaction:
Fe2+Fe3++1eFe^{2+} \rightarrow Fe^{3+} + 1e^-
C2O422CO2+2eC_2O_4^{2-} \rightarrow 2CO_2 + 2e^-
Combined: FeC2O4Fe3++2CO2+3eFeC_2O_4 \rightarrow Fe^{3+} + 2CO_2 + 3e^-
Next, balance the reduction half-reaction:
MnO4Mn2+MnO_4^- \rightarrow Mn^{2+}
MnO4+8H++5eMn2++4H2OMnO_4^- + 8H^+ + 5e^- \rightarrow Mn^{2+} + 4H_2O
Now, multiply the oxidation half-reaction by 5 and the reduction half-reaction by 3 to balance the electrons:
5FeC2O45Fe3++10CO2+15e5FeC_2O_4 \rightarrow 5Fe^{3+} + 10CO_2 + 15e^-
3MnO4+24H++15e3Mn2++12H2O3MnO_4^- + 24H^+ + 15e^- \rightarrow 3Mn^{2+} + 12H_2O
Combine the balanced half-reactions:
5FeC2O4+3MnO4+24H+5Fe3++10CO2+3Mn2++12H2O5FeC_2O_4 + 3MnO_4^- + 24H^+ \rightarrow 5Fe^{3+} + 10CO_2 + 3Mn^{2+} + 12H_2O
From the balanced equation, 5 moles of FeC2O4FeC_2O_4 react with 3 moles of KMnO4KMnO_4.
Therefore, 1 mole of FeC2O4FeC_2O_4 will react with 35\frac{3}{5} moles of KMnO4KMnO_4.

3. Final Answer

3/5

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